What would be a good clear coat to use that can withstand the head of the engine?
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VHT makes one. A friend of mine used it to clearcoat his valve covers at one time. Sorry, I don't know the exact product name or number.
Edit: correction, it wasn't VHT. This was a few years ago and my memory is fading. Oops.
I know Rustoleum makes engine enamel. See if they have one in clear.