If a a center bolt is used, a gasketing washer would be needed to minimize gas leakage and gas fume leakage around the bolt.
To build on this idea... one could use the top of the existing boot as the gasket. Cut it so that the crosscut profile looks like an upside down "U". Now take the metal and put a lip around it like a jar lid (building from Farrar's post) so that it stays centered over the gasket. This is where a little adhesive would help to hold the two pieces together.
If the adhesive works well then the bolt is not needed (and maybe not the lip as well). Simply hose clamp the gasket to the tank lip like it is today.
Another method, which I'm still lukewarm on, is to bolt through the top part of the upside down "U" gasket through the metal disk to secure the two. This would still need sealant between the gasket and the metal plate. And the screws might pull through the rubber boot material... A metal ring inside the upside down "U" would minimize tear-through.
The more I think about this the more options...
Cut the existing boot so that it looks like an upside down "J" with the longer leg inside the tank. Use angle brackets with one leg against the gasket and the other the top. Use sealant between the metal top and the top of the "J" gasket. To prevent gasket pull-through a flat metal band could encircle the boot where the screws/rivets go through. The top could be spot welded or bolted (use sealant) to the brackets
BTW ... if metal is used for the seal/cover, the pump's electrical ground connection could use the metal (in other words, no electrical isolation from the metal seal. Then only one wire would need to pass through the tank wall. But... when removing the tank cover, the electrical connection may hinder its removal).
NK
Reminder: I'm "subject to being wrong without notice."
